Search results for "katalizatory postmetalocenowe"

showing 2 items of 2 documents

Kluczowa rola katalizatora w rozwoju poliolefin

2008

olefin polymerization catalystspoliolefinypolimeryzacja olefinkatalizatorkatalizatory metaloorganiczneorganometalic catalystskatalizatory polimeryzacji olefinpost-metallocene catalystsZiegler-Natta catalystskatalizatory postmetalocenowepolyolefinsolefin polymerizationkatalizatory Zieglera-NattycatalystPrzemysł Chemiczny

researchProduct

Metal salen complexes as ethylene polymerization catalysts - effect of catalytic system composition on its activity and properties of polymerization …

2008

Zsyntetyzowano i zastosowano [po aktywacji metyloaluminoksanem (MAO) lub Et2AlCl] w charakterze katalizatorów niskociśnieniowej polimeryzacji etylenu serię salenowych kompleksów metali przejściowych różniących się rodzajem atomu centralnego (M=Ti, Zr lub V) i budową chemiczną ligandu (schemat A). Stwierdzono, że salenowe kompleksy cyrkonu są aktywne w polimeryzacji jedynie wówczas, gdy aktywator stanowi MAO, natomiast kompleksy tytanu i wanadu są aktywniejsze w przypadku gdy kokatalizatorem jest typowy związek glinoorganiczny - dietylochloroglin. Aktywność kompleksów w układzie z Et2AlCl zmienia się w szeregu V>Ti>>Zr?0, podczas gdy w odniesieniu do kompleksów aktywowanych MAO maleje ona w …

salenowe kompleksy metalipolyethyleneaktywnośćoligomerypolymerizationactivitysalen complexes of metalspost-metallocene catalystspolietylenoligomerskatalizatory postmetalocenowepolimeryzacjaPolimery

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PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
  - PE2_2 Phenomenology of fundamental interactions
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  - PE2_6Nuclear, hadron and heavy ion physics
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  - PE2_7Nuclear and particle astrophysics
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  - PE2_10Atomic, molecular physics
  - PE2_11Ultra-cold atoms and molecules
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LSLife Sciences
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- LS2Integrative Biology: from Genes and Genomes to Systems
  - LS2_1Genetics
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- LS9Biotechnology and Biosystems Engineering
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SHSocial Sciences and Humanities
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- SH6The Study of the Human Past
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